全文获取类型
收费全文 | 86167篇 |
免费 | 7409篇 |
国内免费 | 3600篇 |
专业分类
电工技术 | 3750篇 |
技术理论 | 8篇 |
综合类 | 7851篇 |
化学工业 | 15362篇 |
金属工艺 | 1584篇 |
机械仪表 | 1957篇 |
建筑科学 | 13382篇 |
矿业工程 | 4992篇 |
能源动力 | 5122篇 |
轻工业 | 5038篇 |
水利工程 | 18712篇 |
石油天然气 | 7667篇 |
武器工业 | 198篇 |
无线电 | 1225篇 |
一般工业技术 | 3906篇 |
冶金工业 | 3217篇 |
原子能技术 | 1121篇 |
自动化技术 | 2084篇 |
出版年
2024年 | 132篇 |
2023年 | 911篇 |
2022年 | 1823篇 |
2021年 | 2258篇 |
2020年 | 2461篇 |
2019年 | 2088篇 |
2018年 | 2016篇 |
2017年 | 2460篇 |
2016年 | 2808篇 |
2015年 | 2779篇 |
2014年 | 5310篇 |
2013年 | 5311篇 |
2012年 | 6585篇 |
2011年 | 6568篇 |
2010年 | 4844篇 |
2009年 | 5064篇 |
2008年 | 4459篇 |
2007年 | 5926篇 |
2006年 | 5523篇 |
2005年 | 5077篇 |
2004年 | 3956篇 |
2003年 | 3619篇 |
2002年 | 3145篇 |
2001年 | 2521篇 |
2000年 | 2038篇 |
1999年 | 1557篇 |
1998年 | 1134篇 |
1997年 | 940篇 |
1996年 | 728篇 |
1995年 | 682篇 |
1994年 | 500篇 |
1993年 | 380篇 |
1992年 | 303篇 |
1991年 | 236篇 |
1990年 | 175篇 |
1989年 | 187篇 |
1988年 | 113篇 |
1987年 | 126篇 |
1986年 | 95篇 |
1985年 | 95篇 |
1984年 | 89篇 |
1983年 | 53篇 |
1982年 | 27篇 |
1981年 | 9篇 |
1980年 | 16篇 |
1979年 | 17篇 |
1978年 | 3篇 |
1977年 | 8篇 |
1976年 | 5篇 |
1951年 | 8篇 |
排序方式: 共有10000条查询结果,搜索用时 156 毫秒
11.
12.
《International Journal of Hydrogen Energy》2022,47(49):21033-21043
Magnetron sputtered low-loading iridium-ruthenium thin films are investigated as catalysts for the Oxygen Evolution Reaction at the anode of the Proton Exchange Membrane Water Electrolyzer. Electrochemical performance of 50 nm thin catalysts (Ir pure, Ir–Ru 1:1, Ir–Ru 1:3, Ru pure) is tested in a Rotating Disk Electrode. Corresponding Tafel slopes are measured before and after the CV-based procedure to compare the activity and stability of prepared compounds. Calculated activities prior to the procedure confirm higher activity of ruthenium-containing catalysts (Ru pure > Ir–Ru 1:3 > Ir–Ru 1:1 > Ir pure). However, after the procedure a higher activity and less degradation of Ir–Ru 1:3 is observed, compared to Ir–Ru 1:1, i.e. the sample with a higher amount of unstable ruthenium performs better. This contradicts the expected behavior of the catalyst. The comprehensive chemical and structural analysis unravels that the stability of Ir–Ru 1:3 sample is connected to RuO2 chemical state and hcp structure. Obtained results are confirmed by measuring current densities in a single cell. 相似文献
13.
《International Journal of Hydrogen Energy》2022,47(66):28475-28485
Constructing efficient and stable bifunctional electrocatalysts for overall water splitting remains a challenge because of the sluggish reaction kinetics. Herein, the core-shell hybrids composed of Co(PO3)2 nanorod core and NiFe alloy shell in situ grown on nickel foam (NiFe/Co(PO3)2@NF) are synthesized. Owing to the hierarchical palm-leaf-like structures and strong adhesion between NiFe alloys, Co(PO3)2 and substrates, the catalyst provides a large surface area and rapid charge transfer, which facilitates active sites exposure and conductivity enhancement. The interfacial effect in the NiFe/Co(PO3)2 core-shell structure modulates the electronic structure of the active sites around the boundary, thereby boosting the intrinsic activity. Benefiting from the stable structure, the durability of the catalyst is not impaired by the inevitable surface reconfiguration. The NiFe/Co(PO3)2@NF electrode presents a low cell voltage of 1.63 V to achieve 10 mA cm?2 and manifests durability for up to 36 h at different current densities. 相似文献
14.
15.
Jing Zhang Meili Zhang Yakun Zhang Xue Bai Chen Wang 《International Journal of Food Science & Technology》2022,57(4):2113-2125
As a non-thermal processing technology, high hydrostatic pressure (HHP) can be used for starch modification without affecting the quality and flavour constituents. The effect of HHP on starch is closely related to the treatment pressure of HHP. In this paper, we investigated the impacts of HHP treatment pressure (0, 100, 200, 300, 400, 500, 600 MPa) on the microstructure and retrogradation characteristics of oat starch, established the retrogradation kinetic model and elaborated the mechanism of HHP treatment inhibiting the retrogradation of oat starch. Results show that HHP treatment caused the microstructure of oat starch experienced crystallisation perfection (100–300 MPa), crystallisation destruction (400 MPa), crystallisation disintegration and gelatinisation (500–600 MPa). Results of oat starch retrogradation showed that, after treated at 500 MPa for 15 min, the recrystallisation rate of oat starch was reduced, the formation of nuclei at the early stage of oat starch retrogradation suppressed and its nucleation mode was changed from instantaneous to spontaneous, otherwise, the mobility of water in oat starch gel system reduced. Therefore, 500 MPa treated for 15 min can inhibits the retrogradation of oat starch. This study provides theoretical guidance for the application of HHP technology in starch modification and food processing. 相似文献
16.
Jiachen Wang Jian Li Rui Wang Fei-Yue Xu Xin-An Zeng 《International Journal of Food Science & Technology》2022,57(2):791-800
Frozen poultry meat is the most widely consumed animal-based food. However, water loss often leads to quality loss of poultry meat. Therefore, the present study sought to investigate the combined effect of calcium chloride (CaCl2) and pulsed electric fields (PEF) treatment on chicken breast meats and the mechanisms underlying protein degradation. The results showed that the synergistic effect was superior to the single treatment. Compared with the untreated group, the combination of CaCl2 and PEF increased water holding capacity of chicken breast meats by 16.61% and decreased cooking loss by 28.93%. Low-field nuclear magnetic resonance (LF-NMR) results indicated that the synergistic treatment promoted water molecules' binding capacity in myofibrils of poultry meat, which exhibited higher immobilised water. Additionally, the combination of CaCl2 and PEF led to increased degradation of proteins of high-molecular weight and surface hydrophobicity of myofibrillar protein. Furthermore, the extension of the protein molecule and microenvironmental changes promoted interaction between protein and water. In conclusion, the synergistic treatment of CaCl2 and PEF enhanced water retention and improved physicochemical properties of the myofibrillar protein in chicken breast meats. 相似文献
17.
“十四五”期间,通过强化供水工程运行管理,巩固维护好已建农村供水工程成果,是水利部门实施乡村振兴的基本任务。2021年4月,《安徽省农村供水工程运行管理指南(试行)》正式印发实施。《指南》是在安徽省农村供水工作重点由工程建设转入运行管理的背景下,指导推进农村供水工程规范化管理的重要文件。通过介绍《指南》编制的有关背景、编制目标和特点,解析《指南》的主要内容和条款,可帮助供水管理人员快速掌握《指南》要点,助力《指南》在安徽省内贯彻和实施。 相似文献
18.
《International Journal of Hydrogen Energy》2022,47(43):18587-18596
The development of cost-effective bifunctional catalysts with excellent performance and good stability is of great significance for overall water splitting. In this work, NiFe layered double hydroxides (LDHs) nanosheets are prepared on nickel foam by hydrothermal method, and then Ni2P(O)–Fe2P(O)/CeOx nanosheets are in situ synthesized by electrodeposition and phosphating on NiFe LDHs. The obtained self-supporting Ni2P(O)–Fe2P(O)/CeOx exhibit excellent catalytic performances in alkaline solution due to more active sites and fast electron transport. When the current density is 10 mA cm?2, the overpotential of hydrogen evolution reaction and oxygen evolution reaction are 75 mV and 268 mV, respectively. In addition, driven by two Ni2P(O)–Fe2P(O)/CeOx electrodes, the alkaline battery can reach 1.45 V at 10 mA cm?2. 相似文献
19.
《International Journal of Hydrogen Energy》2022,47(61):25511-25521
Metal/carbon composite materials are highly promising electrocatalysts for water electrolysis. In this work, three composites of metal cobalt nanoparticles highly dispersed in N-doped carbon materials were facilely constructed by pyrolysis of different phenylenediamine based Schiff base-Co complexes (PDBs). Interestingly, the composites derived from PDBs based on different phenylenediamine exhibited different morphologies. The superior case is that rodlike composite catalyst was derived from o-phenylenediamine based PDBs. The obtained catalyst exhibited remarkable performances for both cathodic hydrogen evolution reaction (HER) and anodic oxygen evolution reaction (OER), as well as overall water electrolysis. Only 172 and 289 mV of overpotentials and 1.57 V of cell voltage were exhibited at 10 mA cm?2 for HER, OER and water splitting in 1.0 M KOH, respectively. The catalyst also displayed robust stability and high Faraday efficiency, and thus are potential high-performance catalyst for commercial water electrolysis. 相似文献
20.